Handbook of Ionization Spectra
CONTENT
PREFACE
 
1. PHYSICAL ASPECTS OF IONIZATION SPECTROSCOPY TECHNIQUE
1.1. The nature of ionization spectra
1.2. The role of elastic scattering in ionization spectrum formation for reflection geometry
1.3. Inelastic electron scattering
1.4. IL contour
1.5. Fine structure of ionization spectrum
1.6. Ionization losses
1.7. Opportunities of ionization spectroscopy
 
2. IONIZATION SPECTROSCOPY EQUIPMENT
2.1. Electron spectrometer
2.2. Electron gun
 
3. IL DETECTION
3.1. Detection specifics
3.2. Acceleration voltage fluctuations
3.3. Auger lines suppression
 
4. ADJUSTMENT OF SPECTROMETER'S ELECTRON OPTICS
 
5. SPECTROMETER CALIBRATION
5.1. The goal of calibration
5.2. Calibration of kinetic energy scale
5.3. Electron energy loss scale
5.4. Inspection of spectrometer’s adjustment and calibration
 
6. INTENSITY OF IONIZATION LINES
6.1. IL intensity
6.2. Primary electron energy selection
 
7. SURFACE ANALYSIS BY MEANS OF IS
7.1. Qualitative composition analysis technique
7.2. Standard samples technique
7.3. Elemental sensitivity coefficients technique
7.4. Analysis depth
7.5. Investigation of chemical bonding between the atoms
 
References
Ionisation Spectroscopy: Physical Background and Usage (Contents) On-line Library of IS spectra Info System Software and Library   About Authors

5. SPECTROMETER CALIBRATION

5.2. Calibration of kinetic energy scale

The energy scale E in IS, called kinetic energy scale (see note), is less convenient than the energy loss scale deltaE based on the former. Naturally, the errors in deltaE measurement contain the errors in E scale calibration.

Kinetic energy scale calibration E (eV) [Ref 9] is done with the EBE line, which is assumed to have the same position as Ep.
A number of factors limit the precision of this widely used method:

  • the contact potential difference between the cathode and the internal electrode of the analyzer;
  • energetic spread of primary electrons during thermal emission (see note);
  • energetic spread of primary electrons, due to voltage drop in the directly heated cathode of the electron gun (see note);
  • nonlinear dependency E(Va) (see note);
  • neglecting of relativistic effects (see note);
  • neglecting the recoil energy in elastic scattering (see note);
  • the errors in acceleration voltage measuremennts (see note) Vp, and the voltage Va on the analyzer.

    The estimates show that, with these errors, the spectrometers of the same type will produce results within up to 1.35 eV difference. This corresponds to the main error of 0.7 eV.


  • Look further: 5.3. Electron energy loss scale

    "Handbook of Ionization Spectra"
    ISBN 966-02-1954-7
    © T. Afanasieva, I. Koval,V. Lysenko, P. Mel'nik, N. Nakhodkin, M. Pyatnitsky
    Ukrainian National Academy of Science, Ukrainian Ministry of Education and Science
    Taras Schevchenko University, Radiophysical department
    tel.: +38(044)526-05-60
    e-mail: afanasieva@univ.kiev.ua