Handbook of Ionization Spectra
CONTENT
PREFACE
 
1. PHYSICAL ASPECTS OF IONIZATION SPECTROSCOPY TECHNIQUE
1.1. The nature of ionization spectra
1.2. The role of elastic scattering in ionization spectrum formation for reflection geometry
1.3. Inelastic electron scattering
1.4. IL contour
1.5. Fine structure of ionization spectrum
1.6. Ionization losses
1.7. Opportunities of ionization spectroscopy
 
2. IONIZATION SPECTROSCOPY EQUIPMENT
2.1. Electron spectrometer
2.2. Electron gun
 
3. IL DETECTION
3.1. Detection specifics
3.2. Acceleration voltage fluctuations
3.3. Auger lines suppression
 
4. ADJUSTMENT OF SPECTROMETER'S ELECTRON OPTICS
 
5. SPECTROMETER CALIBRATION
5.1. The goal of calibration
5.2. Calibration of kinetic energy scale
5.3. Electron energy loss scale
5.4. Inspection of spectrometer’s adjustment and calibration
 
6. INTENSITY OF IONIZATION LINES
6.1. IL intensity
6.2. Primary electron energy selection
 
7. SURFACE ANALYSIS BY MEANS OF IS
7.1. Qualitative composition analysis technique
7.2. Standard samples technique
7.3. Elemental sensitivity coefficients technique
7.4. Analysis depth
7.5. Investigation of chemical bonding between the atoms
 
References
Ionisation Spectroscopy: Physical Background and Usage (Contents) On-line Library of IS spectra Info System Software and Library   About Authors

5. SPECTROMETER CALIBRATION

5.1. The goal of calibration

Calibration is a determination of the error of the measurement device which was initially preset for the units corresponding to the dimensionality of the investigated physical quantity.

    The goal of IS spectrometer calibration is to determine the errors in measurement of:
  • energy loss deltaE (eV);
  • normalised IL intensity.


The calibration of the IL intensity scale is a more difficult task than the energy scale calibration. That is why the quantitative anlysis in IS is a problem yet to be solved completely. It requires additional determination of the spectrometer's transmission function and the spectrometer's operator [Ref 2, Ref 3] and note.


Look further: 5.2. Calibration of kinetic energy scale

"Handbook of Ionization Spectra"
ISBN 966-02-1954-7
© T. Afanasieva, I. Koval,V. Lysenko, P. Mel'nik, N. Nakhodkin, M. Pyatnitsky
Ukrainian National Academy of Science, Ukrainian Ministry of Education and Science
Taras Schevchenko University, Radiophysical department
tel.: +38(044)526-05-60
e-mail: afanasieva@univ.kiev.ua