Handbook of Ionization Spectra
CONTENT
PREFACE
 
1. PHYSICAL ASPECTS OF IONIZATION SPECTROSCOPY TECHNIQUE
1.1. The nature of ionization spectra
1.2. The role of elastic scattering in ionization spectrum formation for reflection geometry
1.3. Inelastic electron scattering
1.4. IL contour
1.5. Fine structure of ionization spectrum
1.6. Ionization losses
1.7. Opportunities of ionization spectroscopy
 
2. IONIZATION SPECTROSCOPY EQUIPMENT
2.1. Electron spectrometer
2.2. Electron gun
 
3. IL DETECTION
3.1. Detection specifics
3.2. Acceleration voltage fluctuations
3.3. Auger lines suppression
 
4. ADJUSTMENT OF SPECTROMETER'S ELECTRON OPTICS
 
5. SPECTROMETER CALIBRATION
5.1. The goal of calibration
5.2. Calibration of kinetic energy scale
5.3. Electron energy loss scale
5.4. Inspection of spectrometer’s adjustment and calibration
 
6. INTENSITY OF IONIZATION LINES
6.1. IL intensity
6.2. Primary electron energy selection
 
7. SURFACE ANALYSIS BY MEANS OF IS
7.1. Qualitative composition analysis technique
7.2. Standard samples technique
7.3. Elemental sensitivity coefficients technique
7.4. Analysis depth
7.5. Investigation of chemical bonding between the atoms
 
References
Ionisation Spectroscopy: Physical Background and Usage (Contents) On-line Library of IS spectra Info System Software and Library   About Authors

NOTE

Commercial Auger spectrometers are not always suited for direct measurement, therefore the user may have to modify the setup with a terminal of artificial middle point of the cathode. Another way is to find by considering the voltage drop across the cathode.
The calibration is performed in the following manner.

  • 1. The sign and value of the voltage Víàê is measured on the cathode terminals with the normal operational current through the cathode, while the voltage is turned off.
  • 2. The source of is then turned on and the voltage is measured between the common electrode of electron energy analyzer and the cathode's terminal to which the Víàê sign was referenced. The real voltage is equal to Vð.real= +0.5Vinj, taking into account the sign of Vinj.
  • 3. The voltage , corresponding to the maximum EBE current on the analyzer's exit is measured. For this, the modulation magnitude is set to = 0.5 V and the derivative of the EBE line is recorded. Changing Và, the zero signal is achieved (this corresponds to the maximum EBE current on the analyzer's exit). The value of is measured on the control terminals of the scanning unit after turning off the voltage. The calculated ratio allows to adjust the scale of the digit-to-analog converter of the scanning unit. If the converter's error (for example, 1.4% E) is unacceptable, then the value of E is calculated with the formula (5.1.3) having the calibration error.

  • "Handbook of Ionization Spectra"
    ISBN 966-02-1954-7
    © T. Afanasieva, I. Koval,V. Lysenko, P. Mel'nik, N. Nakhodkin, M. Pyatnitsky
    Ukrainian National Academy of Science, Ukrainian Ministry of Education and Science
    Taras Schevchenko University, Radiophysical department
    tel.: +38(044)526-05-60
    e-mail: afanasieva@univ.kiev.ua