Handbook of Ionization Spectra

CONTENT

1. PHYSICAL ASPECTS OF IONIZATION SPECTROSCOPY TECHNIQUE

1.1. The nature of ionization spectra

1.2. The role of elastic scattering in ionization spectrum formation for reflection geometry

1.3. Inelastic electron scattering

1.4. IL contour

1.5. Fine structure of ionization spectrum

1.6. Ionization losses

1.7. Opportunities of ionization spectroscopy

2. IONIZATION SPECTROSCOPY EQUIPMENT

2.1. Electron spectrometer

2.2. Electron gun

3. IL DETECTION

3.1. Detection specifics

3.2. Acceleration voltage fluctuations

3.3. Auger lines suppression

4. ADJUSTMENT OF SPECTROMETER'S ELECTRON OPTICS

5. SPECTROMETER CALIBRATION

5.1. The goal of calibration

5.2. Calibration of kinetic energy scale

5.3. Electron energy loss scale

5.4. Inspection of spectrometer’s adjustment and calibration

6. INTENSITY OF IONIZATION LINES

6.1. IL intensity

6.2. Primary electron energy selection

7. SURFACE ANALYSIS BY MEANS OF IS

7.1. Qualitative composition analysis technique

7.2. Standard samples technique

7.3. Elemental sensitivity coefficients technique

7.4. Analysis depth

7.5. Investigation of chemical bonding between the atoms

MULTIPLET LEVEL SPLITTING

The reason for multiplet level splitting are the relativistic effects (mainly spin-orbital interaction). The number of components into which the level splits is determined by the total spin number [Ref 3].

"Handbook of Ionization Spectra"
ISBN 966-02-1954-7
Š T. Afanasieva, I. Koval,V. Lysenko, P. Mel'nik, N. Nakhodkin, M. Pyatnitsky
Ukrainian National Academy of Science, Ukrainian Ministry of Education and Science
Taras Schevchenko University, Radiophysical department
tel.: +38(044)526-05-60
e-mail: afanasieva@univ.kiev.ua